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![]() H 2CO 3 HON HNO HNO 2 HNO 3 H 2O 2 HOF HOCl H 2N 2 H 2N=N N 2H 4 H 2O 2 P 2H 4 H 2S H 2S 2 HF HCl HCN HCN triplet HNC HNCO HOCN HONC HCNO HNCS HSCN HN 3 NH 4 + NH 3F + NH 3Cl + H 3O + H 3O 2 + H 2F + PH 4 + H 3S + H 2Cl + H 2CN + Many More Period 4 Compounds, Ga, Ge, As, Se, and Br Acids Many More Period 3 Compounds, Al, Si, P, S, and Cl Many More Triatomic molecules and their Anions, Cations, and Radicals Many More Binary Hydrides and their Anions, Cations, and Radicals P 2 PCl 3 SO 2 SO 3 SO 3 - SOCl 2 SO 2Cl 2 ClO 2 ClOO ClO 2 + ClO 2 - ClOO. OF 2 FOO FOOF FNO 2 FOON F 3 - Cl 3 - Cl 3F ClF 2 + HNCl + NH 2Cl N 3Cl NCl 2 NCl 3 NOCl ONCl NClO ClNO 2 ClNOO t-ClONO OCl 2 ONOOH N 2H 2 N 2H 2 triplet H 2NN H 2NN triplet NH 2F NHF 2 NF 3 NF 4 - N 2F 2 N 2F 4 BNHF N 2O cyclic N 2O cyclic N 2O 2 N 2O 4 NO 2NO NO 2 NO 2 + NO 2 - HOON NOO - NO 2 - triplet N 3 radical N 3 quartet HN 3 N 3 - NCO HNCNH CNNO H 3 + Li 2O BeH 2 BeCl 2 diborane BH 3 BH 2CN BH 2SHīF 3 BF 32- BF 4 + BF 2O - BCl 3 BH 3NH 3 BH 3CO BH 3PH 3 BO 2NOĬ 3 C 5 H 2O H 3O + H 4O + O 3 O 4 CO 2 OCS cyclic CO 2 CO 2 - HCO + HOC + Study Questions to help your understanding of some interesting chemistry.Įxample Molecular Orbital Results LiH LiF LiCl LiOH LiCN LiBr C 2 N 2 NO O 2 CO F 2 Structure calculations are done using NBO Analysis. Is available to help you interpret those output sections. As of 07/12/05 there are 1056īest Lewis Structure and Donor Acceptor Interactions Tutorial You can use the Formula Search page or browse the links below. These calculations take time 1-2 hours in some cases. The Molecular Structure Input Form, see below, will allow you to do calculations We use Alain St-Amant's DeFT program (University of Ottawa). Geometry and molecular orbital energies and ab initio for properties). These calculationsĪre done with some of the best available calculation methods (DFT for Molecular orbital theory is based on approximations also. Link at the bottom of the page for the Chime plugin. To see the 3-D structure of the molecules in these pages. Orbitals used to form these localized bonds. This best Lewis structure is presented withįormal electron pair localized bonds and the hybridization of the atomic The best Lewis structure thatįits the molecular orbitals is also calculated, so you can directlyĬompare with your predictions. ![]() The calculations in this database includeīond lengths, angles, atomic charges, the dipole moment,īond orders, and molecular orbital energies. Theoretical calculations are done carefully, we can learn a lot aboutĬhemical structure by comparing our Lewis structures and hybridization ![]() Simple predictions with molecular orbital theory. However, Lewis dot structures and hybridization are approximations Hybridization, are simple models that help predict chemical These theories, which include Lewis structures, VSEPR, and The simple theories of bonding that we learn in General Chemistry are powerfulĪnd useful. Molecular Structure Calculations Molecular Structure CalculationsĬolby Chemistry, Paul J. ![]() The more segments the object has, the more precision you're able to model with. The detail, or the resolution, adds smoothness to the figure. In some cases, you will be able to change the overall resolution of the model, and in others, you will have to set the detail in all dimensions. Just like with the Size, the number, and names of settings dedicated to setting up the level of the detail will differ between shapes. You can also customize the detail, or the resolution, of the object. It's important to note that by typing the values, you are able to set the size of the object beyond what is possible with the slider the reason is that the slider needs a finite point, while when typing, you are only restricted by the size of the grid. ![]() You can choose the object's dimensions by either moving the slider to manipulate the values or by typing the values directly into the textboxes. Those based on circles, like spheres, cylinders, and so on, will have settings pertaining to the Radius of the object, while shape like a Cube will have settings of the Width, Depth, and Height. The number and names of settings dedicated to the Size will differ between different 3D Shapes. How big do you want your model to be? That's the question the Size setting is going to answer. Of course, you will still be able to modify your shapes with the help of other tools, but the settings explained in this article can be accessed only when adding new Shapes. It's important to note that once you finish this process, you won't be able to get back to those settings. You can set here the properties such as size, detail, arc and fill, position, and rotation. Contrary to the previous method, here you can customize your Shape even before it will be added to the grid. By doing so, you will open the Tool Settings panel on the left side of the screen, which will contain all of the unique settings available for the chosen shape. ![]() The second way to add Shapes to the workspace is by clicking on the chosen shape in the drop-down list. It's the quickest way to add shapes, but the downside of this method is that your shape will be created with its default 3D properties, and it will skip the customization process unique to the selected model. The first option is to simply select the shape you want to add from the drop-down list and drag it to any place on the grid. Let's start with adding Shapes to the workspace. ![]() 03:13 Crank YankersS2 E29 Special Ed Loves Spaghetti Special Ed challenges an employee at a restaurant to prove that she loves spaghetti more than he does. To get the most from this site, please enable JavaScript. Crank YankersS2 E29 Hadassah's Baby Two months after using a hot tub, Hadassah realizes that the sperm in the water has impregnated her. ![]() Special Ed : Bread makes me poop Special Ed : Repeated line Donkey Kong. I got yeah yeah I got yeah that's a good one is it in Special Ed : I WANNA GO TO HAWAII I WANNA GO TO HAWAII YAAAAAAAY Special Ed : I like to make poo-snowballs and throw them at people YAAAAAAAAYYY Backwoodsman : Sounds to me like you're low-bred.I got mail yehey I got mail I got mail I got mail I got mail I got now.Does that mean I got lower standards 'cause I use I got mail.Do you have a discount for special people.But the yeah I could bring to my friends.See also: Special ed, Special education, List of Ed, Edd n Eddy episodes, Legal (Special Ed album), Revelations (Special Ed album), Ed, Edd n Eddy, He is an American rapper and producer, known professionally as Special Ed. Ed is not present in the 2019 revival due to the character being deemed too offensive for modern audiences and he's retired.Ed is perhaps best known for the songs "I Got It Made", "Think About It" and "I'm the Magnificent" from his debut album Youngest in Charge, released in 1989 when he was 17 years old. Puppets are added as the actors to give visual support to what is happening in the phone calls.Crank Yankers featuring Eminem and Denis Leary has one or.Ed makes a cameo in one of Bobby's prank calls, such as the "Let Me Put My Brother on the Phone" call.Calls a community pool and says sorry for peeing in the pool. In the video store call, he works in several references to The Shining. Special Ed is an intellectually immature and disabled 16-year-old who is Bobby Fletchers.In two prank calls of his own (one to a movie theater and one to a video store), Ed reveals that his favorite movie is Air Bud. ![]()
![]() You can up your work hours after the school year or during vacations like spring break. Before you do though, be sure the new job is willing to work with your school schedule. Unless you are doing work that will help you build your final career, think about switching jobs to one that has higher pay. One $100 scholarship may not make that much of a difference, but twenty of those might. Another thing to consider is not overlooking small scholarships. Many colleges have one deadline for all the scholarships – make sure you don’t miss it. Many scholarships go unclaimed every year. Look here for some tips on how to negotiate a raise. Don’t underestimate your worth to an organization. Have you been working at the same job for a while? Ask for a raise. But here are some ways to increase without much – or any – increase in your workload. That is a huge waste of tuition dollars - probably one of your biggest expenses. You don’t want to work so much that you end up not doing well in your classes. You can save money in a number of ways and make more money. Now is the time to take control of your spending habits. If you weren’t happy with how your budget turned out, don’t panic. Not an app person? Excel and Google Sheets both have great templates for tracking your budget without using an app. Mint is one of the most popular apps for budgeting, and depending on what you use, it might integrate well with your tax software. Truebill is a great way to not only track your spending but find and cancel any forgotten subscriptions you aren't using. Here are a couple of the best budget apps for college students. The great news is there are many apps and tools that can help you with that. You need to make sure you are following it. If you aren’t where you need to be, don’t panic! We will get to that part in a minute. Crunch those numbers and see where you are. Food is another variable expense.ĭo the math. If your work hours vary, this might be the case for that income. Note which expenses are fixed expenses and which are variable - meaning they can change from month to month. Scholarship money often comes in at the beginning of the semester as well. For example, you generally buy books at the beginning of the semester. Note which expenses and income are not monthly expenses. Use categories like food, rent, childcare, scholarships, etc. ![]() ![]() Once you have all your expenses, put them into categories. Just put down everything you can think of.Ĭategorize your income and expenses. Don’t worry now about whether it seems to be too much or too little. Gather your info as listed above - all the income and expenses you can think of. If dealing with money makes you nervous, do this step in a pleasant setting, like a coffee shop with your favorite drink. Making a budget can seem overwhelming at first, but it only requires a few steps. But here are a few ideas for some common income and college costs to help with budgeting, especially if you’re doing a budget for the first time: When trying to understand finances in college, there can be different types of income and expenses that will vary from student to student. Let’s go through the different parts of a budget and then go over some tips on how to save money. This will put you in a better financial position after you graduate. College can be very expensive, so it’s important to make sure you are taking out as few student loans as possible and making good financial decisions. What Types of Income and Expenses Can a College Student Have?īudget Tracking Tools for College Studentsīeing organized with your money is one of the most important things you can do to set yourself up for future success. ![]() Refresh your phpinfo page and use the Xdebug wizard again to verify successful installation. On the Configuring Xdebug page in the PhpStorm documentation we should now be down to checking the Xdebug installation. Ok, now you can restart your web server by stopping Apache and then starting it again. Zend_extension="C:\Program Files (x86)\Zend\ZendServer\lib\ZendExtensionManager.dll" Xdebug.profiler_output_dir="C:\Program Files (x86)\Zend\ZendServer\tmp" Zend_extension="C:\Program Files (x86)\Zend\ZendServer\lib\phpext\php_xdebug-2.2." Actually, I did a search for “zend_extension” and put that line of code as well as the following above the current line in my php.ini file with the zend_extension. In step 4 above it says to add the line of code at the top of the file. ![]() If you like Xdebug, and thinks it saves you time and money, please have a look at the donation page. Zend_extension = C:\Program Files (x86)\Zend\ZendServer\lib\phpext\php_xdebug-2.2. Edit C:\Program Files (x86)\Zend\ZendServer\etc\php.ini and add at the begining of the file the line.Open C:\Program Files (x86)\Zend\ZendServer\etc\cfg\debugger.ini and put a in front of the line that says zend_extension_= so that it says zend_extension_=.Move the downloaded file to C:\Program Files (x86)\Zend\ZendServer\lib\phpext.Warning: You seem to be using Zend Server, which is known to cause issues with Xdebug. Go ahead and do the following below except for step 5. NOTE: There’s an extra step that we need to do before we restart our web server in step 5. When I pasted my phpinfo into this wizard and and clicked on the Analyse my phpinfo() output button I got the following output: You can then view the source of this page, select all, copy, and paste into the Xdebug wizard to determine which version of Xdebug you need to download. Save this script as a php file and run it in your browser. To get your phpinfo simply write a script as following: Fortunately, there’s a link under Releases to custom installation instructions which includes a wizard that you can simply paste the source of your phpinfo and it will inform you as to which version of Xdebug you should download. I was a bit confused as to which version of Xdebug I should download. To do that you need to go to the Xdebug download page. This page says we need to install the Xdebug debugging engine. I’ll include several links in this documentation to help walk us through how I got started using PhpStorm and Xdebug.įirst, let’s go to the Configuring Xdebug page in the PhpStorm documentation. I believe the PhpStorm documentation has a good table of contents, is intuitively laid out, has informative contents, and has lots of good links to navigate you where you need to go. One thing I like so far about PhpStorm is the documentation. See more on the Xdebug extension for PHP. ![]() So far, I’m liking PhpStorm the best and in this post I’ll go further into how I got started with Xdebug in PhpStorm.Īs of this writing I’m using Windows 7, Zend Server CE 5.6.0, PHP 5.3.14, PhpStorm 5.0.1, and Xdebug php_xdebug-2.2. Some of the IDE’s I looked at for a replacement were Aptana Studio 3, NetBeans 7.2, PhpStorm 5, and Zend Studio 9. Unfortunately, my old trusty editor does not support some of the new features introduced with PHP 5.3 including namespaces and closures. I’ve been using Zend Studio 5.5.0 as my IDE for as long as I can remember. ![]() In early March, cases began rising in several provinces around the country including Shandong in the east, Guangdong in the south, and Jilin in the northeast.īy the end of the month, the virus had spread to 29 of China’s 31 provinces, according to the National Health Commission (NHC). Here’s what you need to know about the latest outbreak.Ī worker stands in the middle of empty streets, in locked-down Shanghai on April 4. The sustainability of that policy is now under question, as newer, highly infectious Covid variants continue to spread throughout the population. Though this number is still far lower than in many other countries, it’s a dramatic spike for China, which has adhered to a strict zero-Covid strategy that aims to stamp out all outbreaks and chains of transmission using border controls, mass testing, quarantines and stringent lockdowns. On Wednesday, the country recorded close to 20,000 new cases – far past the peak of Wuhan in 2020, at the onset of the pandemic. All 25 million residents are under lockdown, with national health care workers and the Chinese military dispatched to boost the city’s response. Since March, China has battled its biggest Covid wave yet, with Shanghai now the largest hotspot. And public anger is mounting, with no end in sight as China clamps down. ![]() Parents have been forcibly separated from young children infected with Covid-19. ![]() Millions of people across China’s locked-down financial hub of Shanghai have been desperately seeking medical care and basic supplies like food. ![]() Some of my favorite websites to find beautiful, high-quality fonts are Creative Market and Creative Fabrica. For example, you can find free fonts on websites like and. There are many places to find free and paid fonts to download. Once you do that, the new font will be available for you to use in Cricut Design Space. In order to use a new font in Design Space, you’ll need to download the font and install it on your computer. How To Upload Fonts To Cricut Design Space Keep reading to learn how to use all of those fun script fonts in your very own craft projects. I’ll break it down into four easy steps to make it super simple for beginners to get started using their favorite fonts in their designs today! This guide takes all the guesswork out of adding new fonts to Cricut Design Space. ![]() How to Add Fonts to Cricut Design Space on Android.How to Add Fonts to Cricut Design Space on iPhone.How to Add Fonts to Cricut Design Space on iPad.How to Add Fonts to Cricut Design Space on Mac.How to Add Fonts to Cricut Design Space on Windows.How to Access Fonts in Cricut Design Space.How To Upload Fonts To Cricut Design Space.And if you want to be able to use downloaded fonts in your Cricut projects, you’ll need to know how to add them to Design Space.ĭon’t worry it’s actually pretty easy! In this blog post, I’ll show you how to upload fonts in Cricut Design Space so that your projects have that special personalized touch. And if you have a Cricut Access membership, you have even more font options at your fingertips.īut sometimes, you need to search for that perfect font elsewhere. Hooray for a quick win! Keep reading to learn how.Īre you still scrolling through the font menu in Design Space, looking for just the right font to use for your project? (Yep, I’ve been there!)ĭesign Space comes with a bunch of fonts, it’s true. The good news? Uploading fonts to Cricut Design Space is a lot simpler than you may think. (One of those beautiful cursive fonts you saw on Pinterest, perhaps?) Have you ever wanted to upload your own fonts to Cricut Design Space? Sure, Design Space has a ton of free Cricut fonts, but sometimes you just want to use one of your own fonts. ![]()
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